Photochromic lenses have millions of molecules of substances such as silver chloride or silver halide embedded in them. The molecules are transparent to visible light in the absence of UV light, which is normal for artificial lighting. But when exposed to UV rays, as in direct sunlight, the molecules undergo a chemical process that causes them to change shape. The new molecular structure absorbs portions of the visible light, causing the lenses to darken. The number of molecules that change shape varies with the intensity of the UV rays.

When you go indoors and out of the UV light, a different chemical reaction takes place. The absence of the UV radiation causes the molecules to "snap back" to their original shape, resulting in the loss of their light absorbing properties. In both directions, the entire process happens very rapidly.

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